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aspyridone A biosynthesis
| State Icon | Reaction | EC-Number | Confidence maximal confidence score from EnzymeDetector | |
|---|---|---|---|---|
| preaspyridone_A + O2 + reduced_[NADPH-hemoprotein_reductase] <=> aspyridone_A + oxidized_[NADPH-hemoprotein_reductase] + H2O |
1.14.19
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–
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| 4,6-dimethyl-3-oxooctanoyl-[acp] + L-tyrosine + ATP <=> preaspyridone_A + AMP + diphosphate + [acyl-carrier_protein] + H+ |
6.3.2
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–
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| preaspyridone_A + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 14-hydroxypreaspyridone_A + oxidized_[NADPH-hemoprotein_reductase] + H2O |
1.14.13
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–
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| S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + NADPH + H+ + [acyl-carrier_protein] <=> 4,6-dimethyl-3-oxooctanoyl-[acp] + NADP+ + CoA + S-adenosyl-L-homocysteine + H2O + CO2 |
2.3.1
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